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Is is possible to configure the Z-stick as secondary controler from within zwave.me? I want my Harmony 895 to be the primary because it cant be configured as the secondary.

Reset the controller and use Include in another network button once your Harmony is ready to include.

After i've done this, how do i control my lighting through the Z-Stick?

Being secondary controller Z-Way only knows the list of devices in the network, but not their capabilities.

To do this either triple click the button on your light control device or go to Devices Control tab, switch on Expert mode (on the buttom). And then press Request NIF button on the top. Once the NIF will be received, the interview will be automatiaclly completed. Then you would be able to control your devices as you did it with Z-Way as primary.