In Automation/Schedules it is not possible to use multiple times. Also it is not possible to use the time 0-24 hour.
(/smarthome/#/schedules)
Under app/schedule it is possible.
(Schedule
This app allow to control relays, dimmers, thermostats and scenes on a schedule.
Settings:
Pick the time of day
Pick the week days the scene shall be executed
Pick a predefined scene. Such a scene need to be defined using the app “Scene”
Automation Basics
Z-Wave.Me
2.2.2 stable)
Automation/Schedules multiple times in task
Re: Automation/Schedules multiple times in task
v2.2.2 is very old...